Cast member Brad Pitt (L) departs with Angelina Jolie after the world premiere of U.S. director
Steven Soderbergh's film "Ocean's 13" at the 60th Cannes Film Festival May 24, 2007. [Reuters]

Brad Pitt and Angelina Jolie's relationship is on the verge of coming to an end following a furious row between the pair, according to reports.

The couple, who have been dating since 2005, were allegedly involved in an argument which saw the Tomb Raider star throw a glass of red wine over her beau after Pitt accused her of being "immature" during a holiday in France.

Claims have also surfaced the pair have discussed a custody plan to be put in place for kids Maddox, Zahara, Pax and Shiloh in the event of a break up.

A source tells America's Life+Style magazine, "Angie was cursing him and ending up throwing a glass of wine in his face. Brad was absolutely disgusted by her behaviour.

"Brad's had enough of doing what Angie wants to do and following her around the globe."